A stellar athlete, and captain of the archery dojo. Ayako and Rin are actively competing to see who will be the first to snag a boyfriend. Ayako often asks Shirou to come to the archery dojo and watch them practice.
In the anime,
Story spoilers
She is victimized by Rider or Caster early in the story and is later found unconscious in an alleyway. After she is attacked, Ayako is not seen again.
Ayako is seen with Shinji after her disappearance, although Shinji denies it when asked by Shirou.